Changes of Parameters Characteristic for Surface Sediments in Oil Spill Sea Area
XueXue*
*Corresponding
author:XueXue, Key Lab of Marine Environment and
Ecology, Ministry of Education, College of Environmental Science and
Engineering, Ocean University of China,Qingdao, 266100, China. Tel: +86 17854258468;
Email: xuexue931121@163.com
Citation:Xue X(2017) Changes of Parameters Characteristic for Surface Sediments in Oil Spill Sea Area.Arch Pet Environ Biotechnol: APEB -115. DOI: 10.29011/2574-7614. 100115
1.
Abstract
1.
Introduction
2.2
Instruments and
Reagents
2.3
Sample
Preparation
In
the terpanes, the abundance of 17α (H), 21β (H) -22, 29, 30-trisnorhopane(Tm) and 17α (H), 21β (H)-hopance
(C30Hopanes) was the highest. C31, C32
of homohopance were detected more obviously, and the presence of C31 and C32homoHopanesindicated
the influence of petroleum input [5]. In
addition, all samples were detected gammacerane, which gammaceranehave been
found in a lot of crude oiling our country. These indicated that sediments in
the survey area may be affected by oil input. (Figure 3)
shows that for steranes in the sediments of the investigated sea area, and
cholestane, Methylcholestaneand Ethylcholestane in steranewere detected, in
which the geological configurationαββof Steranehad
advantagesobviously.
According
to the study of J P, Bao [6], it is found that
the ratio of Ts/Tm decreases with the increase of biodegradation intensity.
Therefore, it was inferred that the lower Ts/Tm ratio may be related to
biodegradation in four surveys.The component percentage ofR and S configuration
in steranes and terpanes is the important indicatorinassessment of thermal
maturity of organic matter, such as C31~35αβ(S/(S+R)) and C29ααα(S/(S+R)),
etc. They generally show different ranges with different maturity: low maturity
organic matter show between 0.52-0.55, fully mature equilibrium value show of
0.6 or so[7,8]. Therefore, these parameters are
often used to distinguish between oil and non-oil inputs. The ranges of C31αβ (S/(S+R))
ratio in the four surveys were 0.57-0.61, 0.46-0.55, 0.50-0.56
and 0.60-0.64, which all around 0.6; the ranges of C29ααα (S/(S+R))
ratio were0.54-0.57, 0.49-0.54,
0.52-0.55and
0.57-0.62. All of aboveindicated that the survey area had been affected by oil
input.
3.3
Time Variation
of the Characteristic Parameters of Steranes and Terpanes
3.4
Analysis of
Source of Sediment Organic Matter
4.
Conclusion
Figure 1: The surface
sediment sampling sites
Figure 2: GC-MS
Chromatograms of terpanes in sediment from typical sampling station(α, β = 17α (H), 21β (H)-Hopanes; β,α =17β(H), 21α(H)-Hopanes; R
and S = C-22 Rand S configuration; G = Gammacerane; Ts = 18α(H)-22,29,30-Trisnorhopane; Tm = 17α(H)-22, 29, 30-Trisnorhopane)
Figure 3: GC-MS Chromatograms
of steranes in sediment from typical sampling station(ααα
= 5α(H), 14α(H),
17α(H)-steranes; αββ
= 5α(H), 14β(H),
17β(H)-steranes. R and S = C-20 R and S
configuration)
Figure 4: The
distribution diagram of characteristic parameters of steranes and terpanes in
four samplings
Figure 5: Time variation
of the characteristic parameters of steranes and terpanes.
Figure 6: The triangular
diagram of C27-C28-C29αααsteranes
distribution in four times survey.
Station |
1 |
2 |
3 |
4 |
5 |
6 |
7 |
8 |
Mean value |
Ts/Tm |
0.25 |
0.19 |
0.25 |
0.21 |
0.15 |
0.18 |
0.24 |
0.22 |
0.21 |
C29αβ/C30αβ |
0.69 |
0.74 |
0.72 |
0.75 |
0.77 |
0.79 |
0.78 |
0.74 |
0.75 |
C31αβ(S/(S+R)) |
0.60 |
0.60 |
0.60 |
0.61 |
0.61 |
0.58 |
0.57 |
0.61 |
0.60 |
C27αββ/(αββ+ααα) |
0.48 |
0.48 |
0.48 |
0.44 |
0.44 |
0.43 |
0.44 |
0.44 |
0.46 |
C28αββ/(αββ+ααα) |
0.48 |
0.45 |
0.44 |
0.43 |
0.50 |
0.48 |
0.47 |
0.49 |
0.47 |
C29αββ/(αββ+ααα) |
0.40 |
0.39 |
0.39 |
0.39 |
0.39 |
0.39 |
0.40 |
0.40 |
0.39 |
C27αββ/(C27-C29)αββ |
0.28 |
0.29 |
0.29 |
0.29 |
0.23 |
0.25 |
0.26 |
0.25 |
0.27 |
C28αββ/(C27-C29)αββ |
0.35 |
0.31 |
0.30 |
0.32 |
0.38 |
0.38 |
0.35 |
0.37 |
0.34 |
C29αββ/(C27-C29)αββ |
0.38 |
0.40 |
0.40 |
0.40 |
0.39 |
0.37 |
0.39 |
0.38 |
0.39 |
C29ααα(S/(S+R)) |
0.57 |
0.56 |
0.55 |
0.54 |
0.55 |
0.57 |
0.54 |
0.55 |
0.55 |
Table1.1:The characteristic parameters of steranes and terpanes in the surface sediments in November 2015.
Station |
1 |
2 |
3 |
4 |
5 |
6 |
7 |
8 |
Mean value |
Ts/Tm |
0.17 |
0.31 |
0.18 |
0.31 |
0.18 |
0.17 |
0.25 |
0.27 |
0.23 |
C29αβ/C30αβ |
0.80 |
0.77 |
0.92 |
0.86 |
0.94 |
0.88 |
0.87 |
0.78 |
0.85 |
C31αβ(S/(S+R)) |
0.50 |
0.52 |
0.54 |
0.51 |
0.55 |
0.51 |
0.51 |
0.46 |
0.51 |
C27αββ/(αββ+ααα) |
0.39 |
0.39 |
0.37 |
0.37 |
0.38 |
0.38 |
0.37 |
0.37 |
0.38 |
C28αββ/(αββ+ααα) |
0.70 |
0.64 |
0.66 |
0.72 |
0.67 |
0.64 |
0.63 |
0.68 |
0.67 |
C29αββ/(αββ+ααα) |
0.40 |
0.40 |
0.39 |
0.39 |
0.38 |
0.40 |
0.38 |
0.41 |
0.39 |
C27αββ/(C27-C29)αββ |
0.26 |
0.30 |
0.28 |
0.24 |
0.30 |
0.27 |
0.31 |
0.27 |
0.28 |
C28αββ/(C27-C29)αββ |
0.46 |
0.40 |
0.45 |
0.51 |
0.44 |
0.42 |
0.42 |
0.45 |
0.44 |
C29αββ/(C27-C29)αββ |
0.29 |
0.31 |
0.28 |
0.25 |
0.26 |
0.31 |
0.27 |
0.28 |
0.28 |
C29ααα(S/(S+R)) |
0.51 |
0.49 |
0.53 |
0.54 |
0.53 |
0.51 |
0.51 |
0.54 |
0.52 |
Table 1.2: The characteristic parameters of steranes and terpanes in the surface sediments in March 2016.
Station |
1 |
2 |
3 |
4 |
5 |
6 |
7 |
8 |
Mean value |
Ts/Tm |
0.52 |
0.58 |
0.53 |
0.38 |
0.62 |
0.52 |
0.57 |
0.57 |
0.54 |
C29αβ/C30αβ |
0.77 |
0.84 |
0.82 |
0.93 |
0.84 |
0.84 |
0.85 |
0.85 |
0.84 |
C31αβ(S/(S+R)) |
0.56 |
0.50 |
0.52 |
0.53 |
0.54 |
0.53 |
0.51 |
0.50 |
0.52 |
C27αββ/(αββ+ααα) |
0.48 |
0.35 |
0.37 |
0.40 |
0.43 |
0.47 |
0.38 |
0.40 |
0.41 |
C28αββ/(αββ+ααα) |
0.61 |
0.64 |
0.59 |
0.65 |
0.60 |
0.59 |
0.62 |
0.61 |
0.62 |
C29αββ/(αββ+ααα) |
0.38 |
0.33 |
0.35 |
0.36 |
0.38 |
0.37 |
0.37 |
0.43 |
0.37 |
C27αββ/(C27-C29)αββ |
0.35 |
0.29 |
0.32 |
0.31 |
0.35 |
0.34 |
0.31 |
0.28 |
0.32 |
C28αββ/(C27-C29)αββ |
0.40 |
0.44 |
0.41 |
0.41 |
0.38 |
0.40 |
0.43 |
0.43 |
0.41 |
C29αββ/(C27-C29)αββ |
0.25 |
0.27 |
0.27 |
0.28 |
0.26 |
0.26 |
0.26 |
0.29 |
0.27 |
C29ααα(S/(S+R)) |
0.52 |
0.54 |
0.54 |
0.53 |
0.54 |
0.52 |
0.55 |
0.55 |
0.54 |
Table 1.3:The characteristic parameters of steranes and terpanes in the surface sediments in October 2016.
Station |
1 |
2 |
3 |
4 |
5 |
6 |
7 |
8 |
Mean value |
Ts/Tm |
0.56 |
0.55 |
0.50 |
0.53 |
0.59 |
0.43 |
0.53 |
0.51 |
0.53 |
C29αβ/C30αβ |
0.81 |
0.76 |
0.80 |
0.81 |
0.84 |
0.80 |
0.78 |
0.81 |
0.80 |
C31αβ(S/(S+R)) |
0.63 |
0.64 |
0.63 |
0.64 |
0.62 |
0.64 |
0.64 |
0.60 |
0.63 |
C27αββ/(αββ+ααα) |
0.43 |
0.42 |
0.43 |
0.46 |
0.44 |
0.48 |
0.42 |
0.47 |
0.44 |
C28αββ/(αββ+ααα) |
0.50 |
0.48 |
0.48 |
0.52 |
0.51 |
0.55 |
0.50 |
0.51 |
0.50 |
C29αββ/(αββ+ααα) |
0.43 |
0.41 |
0.42 |
0.41 |
0.43 |
0.38 |
0.40 |
0.43 |
0.41 |
C27αββ/(C27-C29)αββ |
0.30 |
0.30 |
0.31 |
0.31 |
0.31 |
0.32 |
0.31 |
0.32 |
0.31 |
C28αββ/(C27-C29)αββ |
0.32 |
0.32 |
0.31 |
0.33 |
0.33 |
0.36 |
0.33 |
0.32 |
0.33 |
C29αββ/(C27-C29)αββ |
0.37 |
0.38 |
0.38 |
0.36 |
0.36 |
0.32 |
0.36 |
0.36 |
0.36 |
C29ααα(S/(S+R)) |
0.62 |
0.59 |
0.60 |
0.60 |
0.60 |
0.57 |
0.61 |
0.59 |
0.60 |
Table1.4:The characteristic parameters of steranes and terpanes in the surface sediments in March 2017.
1. Sun PY, Gao ZH,
Cui WL (2007) Development and application of oil fingerprint identification technology.
China Ocean Press.
4. Ren JX, Ma QM,
Yang XN(2017)Characteristic parameters of organic hydrocarbons in the surface
sediments of Jiaozhou bay[J]. Marine Environmental Science 36:216-221.
7. Peters KE,
Walters CC, Moldowan JM (2005) Biomarkers and Isotopes in the Environment and
Human History.
9. Xu HZ, Zhou CG, Ma
YA, et al. (2001) Study on Specific Biomarkers as the Indicators of Spilled
Oils[J]. Environmental Protection in Transportation 22:5-11.